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The Electrochemical Corrosion

Date:2021-04-21 16:35:50 Hits:1138

The Electrochemical Corrosion

Galvanic corrosion occurs when two different metals have physical or electrical contact with each other and are immersed in a common electrolyte, or when the same metal is exposed to electrolyte with different concentrations. In a galvanic couple, the more active metal (the anode) corrodes at an accelerated rate and the more noble metal (the cathode) corrodes at a slower rate.

In a sense, corrosion can be viewed as the spontaneous return of metals to their ores; the huge quantities of energy that were consumed in mining, refining, and manufacturing metals into useful objects is dissipated by a variety of different routes.

The special characteristic of most corrosion processes is that the oxidation and reduction steps occur at separate locations on the metal. This is possible because metals are conductive, so the electrons can flow through the metal from the anodic to the cathodic regions. The presence of water is necessary in order to transport ions to and from the metal, but a thin film of adsorbed moisture can be sufficient.

Since both the cathodic and anodic steps must take place for corrosion to occur, prevention of either one will stop corrosion. The most obvious strategy is to stop both processes by coating the object with a paint or other protective coating.

One way of supplying this negative charge is to apply a coating of a more active metal. Thus a very common way of protecting steel from corrosion is to coat it with a thin layer of zinc; this process is known as galvanizing.The zinc coating, being less noble than iron, tends to corrode selectively. Dissolution of this sacrificial coating leaves behind electrons which concentrate in the iron, making it cathodic and thus inhibiting its dissolution.

more sophisticated strategy is to maintain a continual negative electrical charge on a metal, so that its dissolution as positive ions is inhibited. Since the entire surface is forced into the cathodic condition, this method is known as cathodic protection. The source of electrons can be an external direct current power supply (commonly used to protect oil pipelines and other buried structures), or it can be the corrosion of another, simply a piece of amore active metal such as zinc or aluminum buried in the ground nearby.

As an alloy, stainless steel will always have more than one metal in contact with air or fluid media. Under the premise that the medium in the pipeline can conduct electricity, electrochemical corrosion will always occur. The CF8M is more difficult to be corroded, but it is not absolutely not corroded.For stainless steel, corrosion is always progressing slowly and firmly.

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